Information on the barrier to internal rotation about the N-nitroso-bond has been obtained for eight saturated cyclic N-nitrosamines by means of variable-temperature proton n.m.r. spectroscopy. Free energies of activation for the process are quoted and are discussed in terms of molecular conformation and group interactions.
R. K. Harris, T. Pryce-Jones and F. J. Swinbourne, J. Chem. Soc., Perkin Trans. 2, 1980, 476 DOI: 10.1039/P29800000476
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