HeI photoelectron spectra of VO2 and V2O3, measured at temperatures above and below the respective semiconductor-to-metal transition temperatures, are reported. Analysis of the vanadium 3d structure in these spectra lends strong support to the established band description of the materials.
N. Beatham, I. L. Fragala, A. F. Orchard and G. Thornton, J. Chem. Soc., Faraday Trans. 2, 1980, 76, 929 DOI: 10.1039/F29807600929
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