The atomization energies, D°0,a, of the new molecules YC3, YC5 and YC6 have been determined by Knudsen cell mass spectrometry as 1805 ± 30, 3081 ± 35 and 3781 ± 60 kJ mol–1, respectively. The trends observed in the atomization energies for polyatomic yttrium carbides follow those of the polyatomic carbon molecules with equal numbers of atoms.
K. A. Gingerich and R. Haque, J. Chem. Soc., Faraday Trans. 2, 1980, 76, 101 DOI: 10.1039/F29807600101
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