The thermal decomposition of the CrIII tris-N-benzoyl-N-phenylhydroxylamine chelate, Cr(BPHA)3, has been investigated using radiometric methods by labelling the complex with 51Cr. The decomposition is found to occur in the temperature range 160–180°C, according to an autocatalytic process. Kinetic models are discussed which should account for the experimental evidence.
J. C. Machado, M. M. Braga, A. M. P. R. Da Luz and G. Duplatre, J. Chem. Soc., Faraday Trans. 1, 1980, 76, 152 DOI: 10.1039/F19807600152
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