Analysis of the fine structure on the LIIIX-ray absorption edge of Au using calculated phase shifts shows that in disodium thiomalato-S-gold(I)(‘Myocrisin’) and thioglucopyranosyl-S-gold(I)(‘Solganol’) the gold(I) atom is bonded to two (bridging) S atoms 2·37 Å; away; EXAFS spectra are compared with that of Na3Au(S2O3)2, a compound of known structure.
M. A. Mazid, M. T. Razi, P. J. Sadler, G. N. Greaves, S. J. Gurman, M. H. J. Koch and J. C. Phillips, J. Chem. Soc., Chem. Commun., 1980, 1261 DOI: 10.1039/C39800001261
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