SCHEDULED MAINTENANCE
When (OC)5MnSiMe3(1) is treated with cyclic ethers (ring size ⩽ 5), ring opening and metal–carbon bond formation occurs; under 200 lb in–2 of CO, high yields of products (OC)5Mn(COR) can be obtained.
K. C. Brinkman and J. A. Gladysz, J. Chem. Soc., Chem. Commun., 1980, 1260 DOI: 10.1039/C39800001260
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