Thermal racemization of optically active 3-methyl-2-phenyl-2H-azirine was found to be 2039 times faster than its rearrangement into 2-methylindole, which furnished firm evidence for the presence of vinyl nitrenes as intermediates.
K. Isomura, G. Ayabe, S. Hatano and H. Taniguchi, J. Chem. Soc., Chem. Commun., 1980, 1252 DOI: 10.1039/C39800001252
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