Issue 24, 1980

Stereochemical requirements of acetylenic retro-ene transition states

Abstract

Retro-ene reactions of acetylenic and olefinic substrates differ in the stereochemical requirements of their respective transition states; reactions of olefins proceed via a chair-like (or boat-like) configuration while those of acetylenes require planarity.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 1247-1248

Stereochemical requirements of acetylenic retro-ene transition states

A. Viola and J. J. Collins, J. Chem. Soc., Chem. Commun., 1980, 1247 DOI: 10.1039/C39800001247

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