The total synthesis of (±)-epi-precapnelladiene (14), containing an uncommon bicyclo[6.3.0]undecane carbon skeleton, is described; the relative stereochemistry of precapnelladiene from Capnella imbricata is established as that in formula (15).
A. M. Birch and G. Pattenden, J. Chem. Soc., Chem. Commun., 1980, 1195 DOI: 10.1039/C39800001195
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