Passing a mixture of two different alkyl halides, in the gas phase, through a column filled with alumina and a phosphonium salt, gives halide-exchange products which are collected at the outlet by condensation; the process is catalytic and allows transformations to be carried out in a continuous flow process.
E. Angeletti, P. Tundo and P. Venturello, J. Chem. Soc., Chem. Commun., 1980, 1127 DOI: 10.1039/C39800001127
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