The ylides derived from the reaction of allylic silylmethylsulphonium salts with n-butyl-lithium rearrange to homoallylic α-methylthiosilanes which are precursors to βγ-unsaturated aldehydes.
P. J. Kocienski, J. Chem. Soc., Chem. Commun., 1980, 1096 DOI: 10.1039/C39800001096
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