6,8a-Ethano-1,2,3,4,5,6,7,8,8a-octahydroisoquinolyl carbinols (3 and 4, R = Et, Ph) undergo rearrangement in concentrated hydrochloric acid to give 3-aza[4.4.4]propellane derivatives (7, R = Et, Ph).
B. C. Uff, M. J. Powell and A. C. W. Curran, J. Chem. Soc., Chem. Commun., 1980, 1059 DOI: 10.1039/C39800001059
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