Issue 21, 1980

Formation and stability of 1,1- and 1,2-bis(dimethylamido)tetrakis(trimethylsiylmethyl)dimolybdenum(Mo[triple bond, length half m-dash]Mo)

Abstract

The reaction of hexane solutions of 1,2-Mo2Br2-(CH2SiMe3)4 with LiNMe2 and HNMe2 gives 1,1- and 1,2-Mo2(NMe2)2(CH2SiMe3)4, respectively, which, once formed, do not isomerize readily.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 985-987

Formation and stability of 1,1- and 1,2-bis(dimethylamido)tetrakis(trimethylsiylmethyl)dimolybdenum(Mo[triple bond, length half m-dash]Mo)

M. H. Chisholm and I. P. Rothwell, J. Chem. Soc., Chem. Commun., 1980, 985 DOI: 10.1039/C39800000985

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