The electrochemical oxidation reactions of cis- and trans-1,3-di-isopropyl-2,4-bis(di-isopropylamino)-cyclodiphospha(III)azane isomers are quite different; only the trans-(1) isomer undergoes a one-electron oxidation reaction to produce a stable radical cation.
A. F. Diaz, O. J. Scherer and K. Andres, J. Chem. Soc., Chem. Commun., 1980, 982 DOI: 10.1039/C39800000982
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