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Issue 19, 1980
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Structural comparison of CuI and CuII complexes displaying analogous N2S2 co-ordination; X-ray analysis of tetraco-ordinate [Cu(pma)]BPh4 and pentaco-ordinate [Cu(pma)SO4][pma[double bond, length as m-dash]2-pyridylmethylbis-(2-ethylthioethyl)amine]

Abstract

The synthesis and X-ray structural characterization of the CuI and CuII complexes [Cu(pma)]BPh4 and [Cu(pma)SO4][pma[double bond, length as m-dash]2-pyridylmethylbis-(2-ethylthioethyl)amine] are reported; both display N2S2 co-ordination with the CuI complex exhibiting trigonal pyramidal geometry while the CuII derivative shows a distorted trigonal bipyramidal geometry which includes a co-ordinated sulphate group.

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Article information


J. Chem. Soc., Chem. Commun., 1980, 906-908
Article type
Paper

Structural comparison of CuI and CuII complexes displaying analogous N2S2 co-ordination; X-ray analysis of tetraco-ordinate [Cu(pma)]BPh4 and pentaco-ordinate [Cu(pma)SO4][pma[double bond, length as m-dash]2-pyridylmethylbis-(2-ethylthioethyl)amine]

K. D. Karlin, P. L. Dahlstrom, J. R. Hyde and J. Zubieta, J. Chem. Soc., Chem. Commun., 1980, 906
DOI: 10.1039/C39800000906

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