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The chemiluminescent properties of several imino-1,2-dioxetans prepared by the photosensitized oxygenation of ketenimines at –78 °C, indicate that the energy level of the transition state for their decompostion to the corresponding ketones and isocyanates is low and that the decomposition proceeds via a biradical mechanism.
Y. Ito, H. Yokoya, K. Kyono, S. Yamamura, Y. Yamada and T. Matsuura, J. Chem. Soc., Chem. Commun., 1980, 898 DOI: 10.1039/C39800000898
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