Apparent ‘long distance’ H-transfers in the fragmentation of steroidal diamines under electron impact result from ‘intramolecular’ ion–molecule reactions between ionic and neutral fragments in the mass spectrometer.
P. Longevialle and R. Botter, J. Chem. Soc., Chem. Commun., 1980, 823 DOI: 10.1039/C39800000823
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