The lack of a significant leaving group effect and the preferential departure of the ‘poorer’ leaving group suggest an irreversible E1cb mechanism for the title reactions.
E. Baciocchi, R. Ruzziconi and G. V. Sebastiani, J. Chem. Soc., Chem. Commun., 1980, 807 DOI: 10.1039/C39800000807
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