Evidence is presented in support of a concerted E2 mechanism for the base hydrolysis of cis-[CoCl2(cyclen)]+(cyclen = 1,4,7,10-tetra-azacyclododecane) in which cleavage of the N–H and Co–Cl bonds occurs synchronously to give a five-co-ordinate intermediate without the intervention of a six-co-ordinate conjugate base.
R. W. Hay and P. R. Norman, J. Chem. Soc., Chem. Commun., 1980, 734 DOI: 10.1039/C39800000734
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