The antiferromagnetic MnII,III,III complex [Mn3(3-Clpy)3O(O2CMe)6], prepared by the reaction of 3-chloropyridine with [Mn(H2O)2(O2CMe)3], possesses a molecular structure, determined by X-ray methods, in which a manganese(II) atom can be clearly distinguished from two manganese(III) atoms.
A. R. E. Baikie, M. B. Hursthouse, L. New, P. Thornton and R. G. White, J. Chem. Soc., Chem. Commun., 1980, 684 DOI: 10.1039/C39800000684
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