Reduction of the P2Mo18O626– anion by two electrons results in the mixed valence form and, by using 31P and 17O n.m.r. high resolution spectra, these electrons are deduced to be firmly trapped by two adjacent molybdenum atoms located in both half-units of the anion.
L. P. Kazansky and M. A. Fedotov, J. Chem. Soc., Chem. Commun., 1980, 644 DOI: 10.1039/C39800000644
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