Issue 14, 1980

Phosphorus-31 and oxygen-17 n.m.r. evidence of trapped electrons in reduced 18-molybdodiphosphate(V), P2Mo18O628–

Abstract

Reduction of the P2Mo18O626– anion by two electrons results in the mixed valence form and, by using 31P and 17O n.m.r. high resolution spectra, these electrons are deduced to be firmly trapped by two adjacent molybdenum atoms located in both half-units of the anion.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 644-646

Phosphorus-31 and oxygen-17 n.m.r. evidence of trapped electrons in reduced 18-molybdodiphosphate(V), P2Mo18O628–

L. P. Kazansky and M. A. Fedotov, J. Chem. Soc., Chem. Commun., 1980, 644 DOI: 10.1039/C39800000644

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