Issue 14, 1980

Reactions of superoxide ion with hydrocarbons activated by the tricarbonylchromium unit

Abstract

The complexation of a Cr(CO)3 unit to certain aromatic hydrocarbons enhances the benzylic position towards attack by superoxide ion in dimethyl sulphoxide; ketones thus produced are also obtainable by treatment of the corresponding benzylic anion complexes with molecular oxygen.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 643-644

Reactions of superoxide ion with hydrocarbons activated by the tricarbonylchromium unit

S. Top, G. Jaouen and M. McGlinchey, J. Chem. Soc., Chem. Commun., 1980, 643 DOI: 10.1039/C39800000643

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