The compound (4a; R2= H), long regarded as a putative intermediate in a chemical model for thymine biosynthesis, has been reformulated as the bis-adduct (4b; R2= H); a chemical model for the action of thymidylate synthetase has been achieved and the result is discussed.
P. A. Charlton and D. W. Young, J. Chem. Soc., Chem. Commun., 1980, 614 DOI: 10.1039/C39800000614
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