Cyclo-octatetraene reacts with [Mo(CO)6] in boiling octane to produce [Mo(CO)4(C16H16)], shown by X-ray diffraction to contain a new dimer of the hydrocarbon arising formally from a combination of [2 + 2]π and [2 + 4]π cycloaddition; the dimer is released as a stable species upon treatment of the complex with Me3NO.
A. H. Connop, F. G. Kennedy, S. A. R. Knox, R. M. Mills, G. H. Riding and P. Woodward, J. Chem. Soc., Chem. Commun., 1980, 518 DOI: 10.1039/C39800000518
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