The addition of ethyl NN-dichlorocarbamate or NN-dichlorophosphoramidates to five-membered cyclic alkenes at 0 °C is stereospecific and cis; these results are conveniently explained by a 1,3-atom shift mechanism.
B. J. Walker and P. J. Wrobel, J. Chem. Soc., Chem. Commun., 1980, 462 DOI: 10.1039/C39800000462
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