Composition and staging in the graphite–AsF6 system and its relationship to graphite–AsF5
Abstract
Interconversion, of graphite–AsF5 intercalates and C12n+AsF6– salts, establishes the equilibrium: 3AsF5+ 2e–⇌ 2AsF6–+ AsF3, for AsF5 intercalation, and simple staging–stoicheiometry relationships exist for both the AsF5 and AsF6– intercalates.