Issue 9, 1980

E.s.r. detection of alkylideneamino radicals in the reaction of nitrogen atoms with alkenes

Abstract

Intermediates formed in the gas-phase reaction of nitrogen atoms with alkenes have been trapped in an inert matrix using a rotating cryostat; e.s.r. examination of the frozen samples has shown the presence of methyleneamino (CH2[double bond, length half m-dash]N·) and alkylideneamino (RCH[double bond, length half m-dash]N·) radicals.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 395-396

E.s.r. detection of alkylideneamino radicals in the reaction of nitrogen atoms with alkenes

P. J. Brooke and B. Mile, J. Chem. Soc., Chem. Commun., 1980, 395 DOI: 10.1039/C39800000395

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