η2-Alkoxythiocarbonyl and chelating Ph2PCHC(R)S-ligands via intramolecular coupling of co-ordinated CS2 and Ph2PCCR; X-ray crystal structure of Fe(CO)[P(OMe)3][Ph2PCHC(But)S][CS(OMe)]

Arthur J. Carty; Fred Hartock; Nicholas J. Taylor; Hubert Le Bozec; Paul Robert; Pierre H. Dixneuf

doi:10.1039/C39800000361

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η²-Alkoxythiocarbonyl and chelating Ph₂PCHC(R)S-ligands via intramolecular coupling of co-ordinated CS₂ and Ph₂PCCR; X-ray crystal structure of Fe(CO)[P(OMe)₃][Ph₂PCHC(Bu^t)S][CS(OMe)]

Arthur J. Carty, Fred Hartock, Nicholas J. Taylor, Hubert Le Bozec, Paul Robert and Pierre H. Dixneuf

Abstract

Reaction of η²-CS₂ complexes, Fe(CS₂)(CO)₂(L¹)(L²) with a phosphino-alkyne Ph₂PC [triple bond, length half m-dash] CBu^t in alcohols, generates, via intramolecular coupling and CS₂ fragmentation, novel derivatives containing η²-alkoxythiocarbonyl and chelating Ph₂PCH [double bond, length half m-dash] C(Bu^t)S-ligands; Fe(CO)[P(OMe)₃][Ph₂PCHC(Bu^t)S][CS(OMe)] has been characterised by X-ray diffraction.

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DOI: https://doi.org/10.1039/C39800000361
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1980, 361-363

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η²-Alkoxythiocarbonyl and chelating Ph₂PCHC(R)S-ligands via intramolecular coupling of co-ordinated CS₂ and Ph₂PCCR; X-ray crystal structure of Fe(CO)[P(OMe)₃][Ph₂PCHC(Bu^t)S][CS(OMe)]

A. J. Carty, F. Hartock, N. J. Taylor, H. Le Bozec, P. Robert and P. H. Dixneuf, J. Chem. Soc., Chem. Commun., 1980, 361 DOI: 10.1039/C39800000361

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Journal of the Chemical Society, Chemical Communications

η²-Alkoxythiocarbonyl and chelating Ph₂PCHC(R)S-ligands via intramolecular coupling of co-ordinated CS₂ and Ph₂PCCR; X-ray crystal structure of Fe(CO)[P(OMe)₃][Ph₂PCHC(Bu^t)S][CS(OMe)]

Abstract

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η²-Alkoxythiocarbonyl and chelating Ph₂PCHC(R)S-ligands via intramolecular coupling of co-ordinated CS₂ and Ph₂PCCR; X-ray crystal structure of Fe(CO)[P(OMe)₃][Ph₂PCHC(Bu^t)S][CS(OMe)]

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