The reaction of the title iron complex with but-3-yn-1-ol yields a 1 : 1 mixture of the η2-2,3-dihydrofuran complex (2) and the 2-oxacyclopentylidene carbene complex (3) while pent-4-yn-1-ol yields the η2-2-methylenetetrahydrofuran complex (6); η2-acetylene and vinylidene carbene complexes are proposed as intermediates.
D. F. Marten, J. Chem. Soc., Chem. Commun., 1980, 341 DOI: 10.1039/C39800000341
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