The hydrogen-bond as a configurational lock in the photocyclisation of dibenzoylmethane o-halogenoanils: wavelength dependence of this reaction
Abstract
The tautomers (1, X
Cl, Br, or I) of anils photocyclise to the phenanthridine derivative (2) with varying efficiencies depending on the halogen and the solvent; owing to the low energies of the first excited states the quantum yields vary with irradiation wavelength.
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