The peroxo TiIV complex, Ti(O2)(edta)2–, is formed by the substitution of O2 on the labile TiIII complex, Ti(edta)(H2O)–, followed by two sequential one-electron reductions forming the co-ordinated peroxo ligand; the analogous reaction with H2O2 in stoicheiometric amounts produces only TiO(edta)2–; edta4–= ethylenediaminetetra-acetate.
F. J. Kristine and R. E. Shepherd, J. Chem. Soc., Chem. Commun., 1980, 132 DOI: 10.1039/C39800000132
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