Issue 2, 1980
From the journal:

Journal of the Chemical Society, Chemical Communications

Five-co-ordinate molybdenum and tungsten complexes, [M(CO)3(PCy3)2], which reversibly add dinitrogen, dihydrogen, and other small molecules

Gregory J. Kubas  

Abstract

New complexes of molybdenum and tungsten with dinitrogen and other small molecules, trans-[M(CO)3(PCy3)2L](L = N2, H2, C2H4, or SO2), have been synthesized by the reaction of [M(CO)3(cycloheptatriene)] with 2PCy3 in the presence of L; removal of L yields the formally five-co-ordinate species [M(CO)3(PCy3)2].

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Article information

DOI
https://doi.org/10.1039/C39800000061
Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 61-62

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Five-co-ordinate molybdenum and tungsten complexes, [M(CO)3(PCy3)2], which reversibly add dinitrogen, dihydrogen, and other small molecules

G. J. Kubas, J. Chem. Soc., Chem. Commun., 1980, 61 DOI: 10.1039/C39800000061

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