SCHEDULED MAINTENANCE
The He(I) photoelectron spectra of monohalogeno- and paradihalogeno-benzenes are reported. Extensive vibrational structure has been observed for ionization from π and lone-pair orbitals and is analysed by reference to frequencies for the neutral molecule. Bands are associated with particular valence shell orbitals by use of ab initio SCF calculations and a simple semi-empirical model.
A. W. Potts, M. L. Lyus, E. P. F. Lee and G. H. Fattahallah, J. Chem. Soc., Faraday Trans. 2, 1980, 76, 556 DOI: 10.1039/F29807600556
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