Issue 19, 1980

XeOF5 and [(XeOF4)3F] anions

Abstract

The XeOF5 and [(XeOF4)3F] anions, which comprise a new class of xenon(VI) oxyfluoro-anion, have been synthesized as their caesium salts and their structures have been characterized for the first time using vibrational spectroscopy and X-ray powder diffraction; the XeOF5 anion displays a stereochemically active lone pair, and the polyanion [(XeOF4)3F] consists of three equivalent XeOF4 groups bonded to an F ion.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 894-897

XeOF5 and [(XeOF4)3F] anions

G. J. Schrobilgen, D. Martin-Rovet, P. Charpin and M. Lance, J. Chem. Soc., Chem. Commun., 1980, 894 DOI: 10.1039/C39800000894

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