Issue 4, 1980

Rapid intramolecular 1,4-hydride transfers in rigid boat-conformation 4-hydroxycyclohexanones

Abstract

The ketols (1a)–(3a), have been prepared and barriers for degenerate rearrangement, by intramolecular hydride transfer, in the derived sodium alkoxides, (1b)–(3b) have been determined from their temperature dependent 13C n.m.r. spectra.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 147-148

Rapid intramolecular 1,4-hydride transfers in rigid boat-conformation 4-hydroxycyclohexanones

G. Craze and I. Watt, J. Chem. Soc., Chem. Commun., 1980, 147 DOI: 10.1039/C39800000147

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