Issue 3, 1979

The additivity of substituent effects in one-bond 13C–1H coupling constants in polysubstituted pyridines

Abstract

The additivity of substituent effects upon one-bond 13C–1H coupling constants in polysubstituted pyridines is described. The substituent effects on 1J(13CH) in monosubstituted pyridines account very well for 1J(13CH) in a variety of polysubstituted pyridines. The additivity relation has some diagnostic value in the assignment of 13C resonances where the chemical shift difference is extremely small.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1979, 285-286

The additivity of substituent effects in one-bond 13C–1H coupling constants in polysubstituted pyridines

Y. Takeuchi and K. Aoki, J. Chem. Soc., Perkin Trans. 2, 1979, 285 DOI: 10.1039/P29790000285

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