Kinetic deuterium isotope effect in the protonation of cryptand [2,1,1], (1,10-diaza-4,7,13,18-tetraoxabicyclo[8.5.5]eicosane) by water
Abstract
The protonation of cryptand [2,1,1] by water displays large kinetic deuterium effects suggesting that the process involves direct proton transfer through the cryptand molecular framework.
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