Issue 10, 1979

Re-examination of the electrochemical reduction of halogeno-silanes and -germanes

Abstract

The electrochemical reduction of halogenosilanes and -germanes in aprotic solvents, to give principally the corresponding dimer, is shown to be an irreversible process taking place at low potentials [–2 to –2·5 V vs. standard calomel electrode (S.C.E.)]; all reduction waves observed at –0·4 V vs. S.C.E. corresponded to the reduction of HCl formed in the hydrolysis.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 457b-458

Re-examination of the electrochemical reduction of halogeno-silanes and -germanes

R. J. P. Corriu, G. Dabosi and M. Martineau, J. Chem. Soc., Chem. Commun., 1979, 457b DOI: 10.1039/C3979000457B

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