Issue 24, 1979

Template effect in intramolecular hydrogen abstraction by acyl nitroxides: preferential 1,6- and 1,7-hydrogen shifts

Abstract

In the series of ω-phenylalkanoyl t-butyl nitroxides (1), n= 1–5, intramolecular hydrogen transfer to oxygen from the benzylic position occurs most readily when n= 3 or 4.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 1167-1168

Template effect in intramolecular hydrogen abstraction by acyl nitroxides: preferential 1,6- and 1,7-hydrogen shifts

C. Berti and M. J. Perkins, J. Chem. Soc., Chem. Commun., 1979, 1167 DOI: 10.1039/C39790001167

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