The preparation of carbonyl-free mixed organotransition metal complexes [(η5-C5H5)2M(µ-H)2Rh(PPh3)2]PF6, (M = Mo or W) in which (η5-C5H5)2MH2 exhibits a novel bonding mode is described, and the X-ray crystal structure of the title compound, which undergoes H–D exchange at the cyclopentadienyl rings under mild conditions, has been determined.
N. W. Alcock, O. W. Howarth, P. Moore and G. E. Morris, J. Chem. Soc., Chem. Commun., 1979, 1160 DOI: 10.1039/C39790001160
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...