The temperature dependence of the 1H and 11B longitudinal relaxation times and of the 1H nuclear shieldings in nido-decaborane (B10H14), in C6D5CD3 solution indicate that there is a transition between anisotropic and essentially isotropic molecular tumbling between ca.–35 and +25 °C; this transition has not previously been observed in solution.
N. N. Greenwood and J. D. Kennedy, J. Chem. Soc., Chem. Commun., 1979, 1099 DOI: 10.1039/C39790001099
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