The isomer isolated from Propionibacterium shermanii cultures together with sirohydrochlorin (1a) is shown by 13C-labelling and nuclear Overhauser effect studies to have structure (5a), i.e. 3-episirohydrochlorin.
A. R. Battersby, E. McDonald, R. Neier and M. Thompson, J. Chem. Soc., Chem. Commun., 1979, 960 DOI: 10.1039/C39790000960
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