A magnetic polarization study of the photochemistry of ortho-substituted methyl phenyl sulphoxides indicates that ortho-substituents promote efficient photodealkylation, through a triplet methyl–arylsulphinyl radical pair, escape and recombination paths of which were both observed.
K. A. Muszkat, K. Praefcke, I. Khait and R. Lüdersdorf, J. Chem. Soc., Chem. Commun., 1979, 898 DOI: 10.1039/C39790000898
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