HOCH2CH2HgX (1; X = Cl) in aqueous base is catalytically decomposed to ethanol and acetate by [Rh2(C5Me5)2(OH)3]Cl·4H2O (2); direct reaction of ethylene with Hg(OAc)2–complex (2) in the presence of base also yields comparable amounts of ethanol, some acetaldhyde also being formed.
J. Cook and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1979, 871 DOI: 10.1039/C39790000871
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