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Issue 19, 1979
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Stereoselective synthesis of arylated (E)-alkenes by the reaction of alk-1-enylboranes with aryl halides in the presence of palladium catalyst

Abstract

The reaction of aryl halides with alk-l-enylboranes, readily obtainable via monohydroboration of acetylenes, provides a conveninet new method for stereoselective synthesis of arylated (E)-alkenes in high yields; these reactions are effectively catalysed by tetrakis(triphenylphosphine)palladium and bases such as sodium ethoxide.

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Article type: Paper
DOI: 10.1039/C39790000866
J. Chem. Soc., Chem. Commun., 1979, 866-867

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    Stereoselective synthesis of arylated (E)-alkenes by the reaction of alk-1-enylboranes with aryl halides in the presence of palladium catalyst

    N. Miyaura and A. Suzuki, J. Chem. Soc., Chem. Commun., 1979, 866
    DOI: 10.1039/C39790000866

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