The reaction of aryl halides with alk-l-enylboranes, readily obtainable via monohydroboration of acetylenes, provides a conveninet new method for stereoselective synthesis of arylated (E)-alkenes in high yields; these reactions are effectively catalysed by tetrakis(triphenylphosphine)palladium and bases such as sodium ethoxide.
N. Miyaura and A. Suzuki, J. Chem. Soc., Chem. Commun., 1979, 866 DOI: 10.1039/C39790000866
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