The synthesis and X-ray crystal structure of Λ-NS-[Co(ethylenediamine)2(S)S-methyl(R)cysteinato]-(NCS)2 are described; sulphur bonding of the sulphide is established, the chiral S-methyl centre is stereospecifically oriented, and rearrangement from the NS to the NO bound isomer was not observed under acidic conditions.
G. J. Gainsford, W. G. Jackson and A. M. Sargeson, J. Chem. Soc., Chem. Commun., 1979, 802 DOI: 10.1039/C39790000802
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