Pressure dependence of the racemization of tris(pyrrolidyldithiocarbamato)-cobalt(III) in non-aqueous solvents
Abstract
From activation volume evidence a twist mechanism incorporating a low-spin → high-spin pre-equilibrium in the transition state is indicated for racemization of Co(pyrdtc)3(pyrdtc = pyrrolidyldithio-carbamato) in non-aqueous solvents.