The reaction of [HOs3(CO)10(CF3CCHCF3)] with PEt3 in hexane at room temperature leads to the formation of [HOs3(CO)10(PEt3)(CF3CCHCF3)] as the major product; a single crystal X-ray analysis reveals the presence of a chain of Os atoms, a terminal hydride ligand, and a vinylic group bridging two of the metal atoms.
Z. Dawoodi, M. J. Mays and P. R. Raithby, J. Chem. Soc., Chem. Commun., 1979, 721 DOI: 10.1039/C39790000721
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