An unusually low selectivity in the site of β-scission of a cyclobutanoxyl radical, resulting in the formation of substantial amounts of a less stabilized alkyl radical, was found when D-nor-5α-androstan-16β-ol nitrite was irradiated with 373 nm monochromatic light.
H. Suginome and T. Uchida, J. Chem. Soc., Chem. Commun., 1979, 701 DOI: 10.1039/C39790000701
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